Didier Astruc's Library

Nanoscience and Catalysis

 
   
 
Review
Publications
Books
Collaborations
 
     
     

 

Why is Ferrocene so Exceptional?.

D. Astruc. Eur. J. Inorg. Chem., 2016, 000. DOI: 10.1002/ejic.201600983


 

Precise Localization of Metal Nanoparticles in Dendrimer Nanosnakes or Inner
Periphery and Consequences in Catalysis.

X. Liu, D. Gregurec, J. Irigoyen, A. Martinez, S. Moya, R. Ciganda, P. Hermange, J. Ruiz, D.
Astruc, Nat. Commun.vol. 7,‎ 2016, (DOI 10.1038/ncomms13152)


 

Base-catalyzed hydrogen-deuterium exchange and dehalogenation reactions of
1,2,3-triazole derivatives
.

D. Wang, S. Chen, J. Wang, D. Astruc, B. Chen., Tetrahedron2016, 72, 6375-6379. doi.org/10.1016/j.tet.2016.08.033.


 

The Dual Functional Epoxy Material with Automatic Damage Indication and Self
Healing.

Y. K. Guo, L. Chen, D. G. Xu, J. R. Zhong, G. Z. Yue, D. Astruc, M. B. Shuai, P. X. Zhao
R S C Adv. 2016, 6, 65067-65071. DOI: 10.1039/C6RA13519F.


 

Supramolecular Nanoreactors for Catalysis.

C. Deraedt, D. Astruc. Coord. Chem. Rev2016, 324, 106-122. DOI: 10.1016/j.ccr.2016.07.007

 


 

Design and applications of an efficient amphiphilic “click” CuI catalyst in water.

C. Wang, D. Wang, S. Yu, T. Cornilleau, J. Ruiz, L. Salmon, D. Astruc. ACS Catal. 2016, 6, 5424−5431.


 

Liquid-Liquid Interfacial Electron Transfer from Ferrocene to Au(III): An Ultra-Simple and Fast Au Nanoparticle Synthesis in  Water Under Ambient Conditions

R.Ciganda, J. Irigoyen, D. Gregurec, R. Hernández, S. Moya, C. Wang, J. Ruiz, D. Astruc, Inorg. Chem2016, 55 (13), pp 6361–6363 http://dx.doi.org/10.1021/acs.inorgchem.6b01183


 

Living ROMP Syntheses and Redox Properties of Triblock Metallocopolymer Redox Cascades.

H. Gu, R. Ciganda, P. Castel, J. Ruiz, D. Astruc. Macromolecules201649 (13), pp 4763–4773 DOI: 10.1021/acs.macromol.6b01046


 

From Mono-to Tris-1,2,3-triazole-Stabilized Gold Nanoparticles and their Compared Catalytic Efficiency in 4-Nitrophenol Reduction

C. Wang, L. Salmon, Q. Li, M. Igartua, S. Moya, R. Ciganda, J. Ruiz, D. Astruc. Inorg. Chem. 2016, DOI 10.1021/acs.inorgchem.6b01092


 

On Metallocene-containing Macromolecules and their Applications

H. Gu, R. Ciganga, S. Gatard, F. Lu, P. Zhao, J. Ruiz, D. Astruc, J. Organomet. Chem2016813, 95-102


 

 Molecular Sieving with Vertically Aligned Mesoporous Silica Films and E lectronic Wiring through Isolating Nanochannels.

N. Vilà, E. André, R. Ciganda, J. Ruiz, D. Astruc, A. Walcarius, Chem. Mater201628, 2511-2514. DOI: 10.102/acs.chemmater.6b00716


 

Metal-Catalyzed Azide-Alkyne “Click” Reactions: Mechanistic Overview and Recent Trends.

Changlong Wang, Djamila Ikhlef, Samia Kahlal, Jean-Yves Saillard, Didier Astruc. Coord. Chem. Rev. 2016316, 1-20. DOI: 10.1016/j.ccr.2016.02.010


 

Diblock Metallocopolymers Containing Various Iron Sandwich Complexes: Living ROMP Synthesis and Selective Reversible Oxidation.

H. Gu, R. Ciganda, R. Hernández, P. Castel, A. Vax, P. Zhao, J. Ruiz, D. Astruc. Polym. Chem2016, 7, 2358-2371. DOI: 10.1039/C6PY00202A


 

Diblock Polyelectrolytic Copolymers Containing Cationic Iron and Cobalt Sandwich Complexes: Living ROMP Synthesis and Redox Properties.

H. Gu, R. Ciganda, P. Castel, P. Zhao, J. Ruiz, R. Hernández, D. Astruc. Macromol. Rapid Commun2016, 37, 630-636. DOI : 10.1002/marc.201500679


 

Highly efficient transition metal nanoparticle catalysts in aqueous solutions.


C. Wang, R. Ciganda,  L. Salmon, D. Gregurec, J. Irigoyen, S. Moya, J. Ruiz, D. Astruc. Angew. Chem. Int. Ed201655, 3091-3095. DOI: 10.1002/anie.201511305


 

Pd/C as an efficient and reusable catalyst for the selective  N-alkylation of amines with alcohols

X. Liu, P. Hermange, J. Ruiz, D. Astruc. ChemCatChem, 2016, March 18, 2016. Volume 8, Issue 6 (pages 1043–1045) DOI: 10.1002/cctc.201501346R1


 

Gold Nanoparticles as Sensors in Colorimetric and Fluorescence Detection of Chemical Warfare Agents

 
P. Zhao, X. Lai, G. Yue, S. Su, N. Li,  D. Astruc,  M. Shuai, Coord. Chem. Rev2016, 311, 75-84



 

 

Introduction to Nanomedicine. Editorial.

 

D. Astruc, Molecules 2016, 21, 4; doi: 10.3390/molecules2101000

 

Living ROMP Synthesis and Redox Properties of Diblock Ferrocene/Cobalticenium Copolymers.

R. Ciganda, H. Gu, P. Castel, P. Zhao, J. Ruiz, R. Hernández, D. Astruc, Macromol. Rapid Commun201637, 105-111. DOI: 10.1002/marc.201500566.


 

 

     

 

Efficient and Magnetically Recoverable “Click” PEGylated γ-Fe2O3–Pd Nanoparticle Catalysts for Suzuki–Miyaura, Sonogashira, and Heck Reactions with Positive Dendritic Effects.


Dong Wang, Christophe Deraedt, Lionel Salmon, Christine Labrugère, Laetitia Etienne, Jaime Ruiz, and Didier Astruc.
Chem. Eur. J. 2015, 21, 1508 – 1519


 

Robust, Efficient, and Recyclable Catalysts from the Impregnation of Preformed Dendrimers Containing Palladium Nanoparticles on a Magnetic Support.


Christophe Deraedt, Dong Wang, Lionel Salmon, Laetitia Etienne, Christine Labrugère, Jaime Ruiz, and Didier Astruc.
ChemCatChem 2015, 7, 303 – 308.


 

Gold Nanosweepers (AuNSs): A Novel Application of PEGylated AuNPs.


Guiying Yang, Na Li, Ho-Yin Chow, Qinying Xu, Huanlin Zhang, Jaime Ruiz,
Xinchun Lai, Didier Astruc, Kwok-Yin Wong, and Pengxiang Zhao.
Chem. Lett. 2015, 44, 191–193 | doi:10.1246/cl.140964


 

The Redox Functions of Metallodendrimers.


Didier Astruc Jaime Ruiz.
J Inorg Organomet Polym (2015) 25:2–11


 

Organoiron-mediated synthesis and redox activity of organoiron-containing dendrimers.


Didier Astruc, Yanlan Wang, Amalia Rapakousiou, Abdou Diallo, Rodrigue Djeda,
Jaime Ruiz, Catia Ornelas.
Polyhedron 86 (2015) 24–30


 

Basic Concepts and Recent Advances in Nitrophenol Reduction by Gold- and Other Transition Metal Nanoparticles.


P. Zhao, X. Feng, D. Huang, G. Yang,  D. Astruc.
 Coord. Chem. Rev. 2015, 287, 114-136.


 

Synthesis and Redox Activity of “Clicked” Triazolylbiferrocenyl Polymers, Network Encapsulation of Gold and Silver Nanoparticles and Anion Sensing.


A. Rapakousiou, C. Deraedt, J. Irigoyen, Y. Wang, N. Pinaud, L. Salmon, J. Ruiz, S. Moya, J. Ruiz, D. Astruc.
Inorg. Chem. 2015, 54, 2284–2299. DOI: 10.1021/ic5028916.


 

Alkynyl-functionalized imidazolium for “click” dendrimer functionalization and palladium nanoparticle stabilization.


C. Deraedt, M. d’Halluin, S. Lesturgez, L. Salmon, G. Goglio, J. Ruiz, D. Astruc.
Eur. J. Inorg. Chem. 2015, 27, 1345-1350. DOI: 10.1002/ejic.201403045


 

Catalytically-Active Palladium Nanoparticles Stabilized by Triazolylbiferrocenyl-Containing Polymers.
C. Deraedt, A. Rapakousiou, H. Gu, L. Salmon, J. Ruiz, D. Astruc.

J. Inorg. Organomet. Polym. Mater. 2015,25, DOI: 10.1007/s10904-014-0161-6 (H. W. Neuse issue).


 

Sodium Hydroxide-Catalyzed Transfer Hydrogenation of Carbonyl Compounds and Nitroarenes Using Ethanol or Isopropanol as Both Solvent and Hydrogen Donor.


D. Wang, C. Deraedt, J. Ruiz, D. Astruc.
J. Mol. Cat. A 2015, 400, 14–21. doi:10.1016/j.molcata.2015.01.024.


 

On the Redox Chemistry of Ferrocenes and Other Iron Sandwich Complexes and its Applications.


D. Astruc, J. Ruiz.
J. Inorg. Organomet. Polym. Mater. 2015, 25, DOI 10.1007/s10904-015-0178-5 (H. W. Neuse issue).


 

A Tris(triazolate) Ligand for a Highly Active and Magnetically Recoverable Palladium Catalyst of Selective Alcohol Oxidation Using Air at Atmospheric Pressure.


D. Wang, C. Deraedt, L. Salmon, C. Labrugère, L. Etienne, J. Ruiz, D. Astruc.
Chem. Eur. J. 2015, 21, 6501 - 6510, DOI: 10.1002/chem.201500122.


 

New Polysilyl Dendritic Precursors of Triazolylferrocenyl and Triazolylcobalticenium Dendrimers, Comparative Electrochemical Study and Stabilization of Small Catalytically-Active Pd Nanoparticles.

S. Gatard, C. Deraedt, A. Rapakousiou, D. Sonet, L. Salmon, J. Ruiz, D. Astruc. Organometallics 2015, 34, 1643-1650. DOI:10.1021/acs.organomet.5b00035.   


 

Click Metallodendrimers and their Functions.

D. Astruc, R. Ciganda, C. Deraedt, S. Gatard, L. Liang, N. Li, C. Ornelas, A. Rapakousiou, J. Ruiz, D. Wang, Y. Wang, P. Zhao,. Synlett 2015, 26, 1437-1449. DOI 10.1055/s-0034-1380699.


 

Catalysis Inside Dendrimers.


Didier Astruc, D. Wang, C Deraedt, L. Liang, R. Ciganda, J. Ruiz.
Synthesis 2015, 47,  2017-2031 DOI: 10.1055/s-0034-1380868.


 

The Golden Age of Transfer Hydrogenation.


D. Wang, D. Astruc.
Chem. Rev. 2015, 115, 6621-6686. DOI 10.1021/acs.chemrev.5b00203.


 

Magnetic and Dendritic Catalysts.


D. Wang, C. Deraedt, J. Ruiz, D. Astruc.
Acc Chem. Res. 2015, 48, 1871-1880. DOI: 10.1021/acs.accounts.5b00039.


 

ROMP Synthesis and Redox Properties of Polycationic Metallopolymers Containing the Electron-Reservoir Complex [Fe(η5-C5H5)(η6-C6Me6)][PF6].


H. Gu, R. Ciganda, R. Hernández, P. Castel, P. Zhao, J. Ruiz and D. Astruc.
Macromolecules 2015, 34, doi.org/10.1021/acs.macromol.5b01603


 

 
 
   

 

Mixed-Valent Click Intertwined Polymer Units Containing Biferrocenium Chloride Side Chains Form Nanosnakes that Encapsulate Gold Nanoparticles .


Amalia Rapakousiou ,  Christophe Deraedt, Haibin Gu,  Lionel Salmon,  Colette Belin, Jaime Ruiz, and  Didier Astruc  

J. Am. Chem. Soc. 2014, 136, 13995−13998

 

Figure

   
   

Sodium borohydride stabilizes very active gold nanoparticle Sodium borohydride stabilizes very active gold.

Christophe Deraedt, Lionel Salmon, Sylvain Gatard, Roberto Ciganda, Ricardo Hernandez, Jaime Ruiz and Didier Astruc.

Chem. Commun. , 2014, DOI: 10.1039/C4CC05946H

Graphical abstract: Sodium borohydride stabilizes very active gold nanoparticle catalysts
 
 
 
 

Recyclable Catalytic Dendrimer Nanoreactor for Part-Per-Million CuI Catalysis of “Click” Chemistry in Water.

Christophe Deraedt,  Noël Pinaud, and  Didier Astruc

J. Am. Chem. Soc. 2014, 136, 12092−12098  

Abstract Image
 
 
 
 

Living Ring-Opening Metathesis−Polymerization Synthesis and Redox-Sensing Properties of Norbornene Polymers and Copolymers Containing Ferrocenyl and Tetraethylene Glycol Groups.

Haibin Gu, Amalia Rapakousiou, Patricia Castel, Nicolas Guidolin, Noel Pinaud,† JaimeRuiz, and Didier Astruc.

Organometallics 2014, 33, 4323−4335

Abstract Image
 
 
 
 

Gold nanoparticles as electron reservoir redox catalysts for 4-nitrophenol reduction: a strong stereo electronic ligand influence

Roberto Ciganda, Na Li, Christophe Deraedt, Sylvain Gatard, Pengxiang Zhao, Lionel Salmon, Ricardo Hernandez, Jaime Ruiza and Didier Astruc

Chem. Commun., 2014, 50, 10126 – 10129

Graphical abstract: Gold nanoparticles as electron reservoir redox catalysts for 4-nitrophenol reduction: a strong stereoelectronic ligand influence
 
 
 
 

Palladium Nanoparticles Stabilized by Glycodendrimers and Their Application in Catalysis.

Sylvain Gatard, Lionel Salmon, Christophe Deraedt, Jaime Ruiz, Didier Astruc, and Sandrine Bouquillon.


Eur. J. Inorg. Chem. 2014, 4369–4375

Link to full-size graphical abstract
 
 
 
 

Nanogold plasmonic photocatalysis for organic synthesis and clean energy conversion.

Changlong Wang and Didier Astruc.


Chem. Soc. Rev., 2014, 43, 7188—7216

Graphical abstract: Nanogold plasmonic photocatalysis for organic synthesis and clean energy conversion
 
 
 
 

Metallodendrimers in Three Oxidation States with Electronically Interacting Metals and Selective Stabilization of Gold Nanoparticles

Yanlan Wang, Lionel Salmon, Jaime Ruiz and Didier Astruc

NATURE COMMUNICATIONS , 2014, DOI: 10.1038/ncomms4489

 
 
 
 

Anisotropic Gold Nanoparticles: Synthesis, Properties, Applications, and Toxicity.

Na Li, Pengxiang Zhao,* and Didier Astruc*

Angew. Chem., Int. Ed . 2014, 52, 1756–1789 

Thumbnail image of graphical abstract
 
 
 
 

‘‘Click’’ Synthesis and Redox Activity of a Water-Soluble Triazolylcobalticinium Polyelectrolyte

Amalia Rapakousiou, Yanlan Wang, Jaime Ruiz, Didier Astruc.

J. Inorg. Organomet. Polym. Mater .  2014 , 24 (1), 107-113 

 
 
 
 

. Homeopathic” Palladium Nanoparticle Catalysis of Cross Carbon-Carbon Couplin Reactions.

Christophe Deraedt and Didier Astruc

 Acc. Chem. Res. 2014 , 47, 494-503

 
 
 
 

A Highly Active and Magnetically Recoverable Tris(triazolyl)–CuI Catalyst for Alkyne–Azide Cycloaddition Reactions

Dong Wang, Laetitia Etienne, Mara Echeverria, Sergio Moya, and Didier Astruc

 Chem. Eur. J. 2014, DOI:10.1002 / chem. 201304536 .
Thumbnail image of graphical abstract
 
 
 
 

Rhodicenium Salts: From Basic Chemistry to Polyelectrolyte and Dendritic Macromolecules.

Amalia Rapakousiou, Lucia Herrer Jimenez, Yanlan Wang, Claire Mouche, and Didier Astruc.

Organometallics  , 2014, 33, 000 dx.doi.org/10.1021/om500028e 

 

 
 
 
 

Gold Nanoparticles Stabilized by Glycodendrimers: Synthesis and Application to the Catalytic Reduction of 4-Nitrophenol

Sylvain Gatard, Lionel Salmon, Christophe Deraedt, Jaime Ruiz, Didier Astruc, and Sandrine Bouquillon.

Eur. J. Inorg. Chem .2014, 2671–2677
 
 
 
 

Uncatalyzed Hydroamination of Electrophilic Organometallic Alkynes: Fundamental, Theoretical, and Applied Aspects.

Yanlan Wang, Camille Latouche, Amalia Rapakousiou, Colin Lopez, Isabelle LedouxRak, Jaime Ruiz, Jean-Yves Saillard, and Didier Astruc.

Chem. Eur. J .2014, 20, 8076 – 8088

 
 
 
 

Click” Chemistry Mildly Stabilizes Bifunctional Gold

Nanoparticles for Sensing and Catalysis

Na Li, Pengxiang Zhao, Na Liu, Maria Echeverria, Sergio Moya, Lionel Salmon, Jaime Ruiz, and Didier Astruc*

Chem. Eur. J . 2014, 20, 8363 – 8369

Thumbnail image of graphical abstract
 
 
 
 

Magnetically Recoverable Ruthenium Catalysts in Organic Synthesis

Dong Wang and Didier Astruc

 
 
 
 

Organoiron-mediated synthesis and redox activity of organoiron-containing dendrimers

Didier Astruc, Yanlan Wang, Amalia Rapakousiou, Abdou Diallo, Rodrigue Djeda, Jaime Ruiz, Catia Ornelas.


Polyhedron 2014 (C.Lapinte issue) doi.org / 10.1016 / j.poly.2014.04.002.

 
 
 
       
 

 

“Click” Dendrimer-Stabilized Palladium Nanoparticles as a Green Catalyst Down to Parts per Million for Efficient C-C Cross-Coupling Reactions and Reduction of 4-Nitrophenol

Christophe Deraedt, Lionel Salmon and Didier Astruc.

Adv. Synth. Catal. 2014, 356, 2525 – 2538

Catalysis by 1,2,3-triazole- and related transition-metal complexes.

Deshun Huanga, Pengxiang Zhaoa, Didier Astruc.

Coordination Chemistry Reviews 272 (2014) 145–165.

 

 


Multifunctional Redox Polymers: Electrochrome, Polyelectrolyte, Sensor, Electrode Modifier, Nanoparticle Stabilizer, and Catalyst Template.

Christophe Deraedt, Amalia Rapakousiou, Yanlan Wang, Lionel Salmon, Melanie Bousquet, and Didier Astruc.

Angew. Chem. Int. Ed . 2014, 53, 8445 –8449

Metalation of Polyamine Dendrimers with Ethynylcobalticenium for the Construction of Mono- and Heterobimetallic Polycationic Metallodendrimers

Yanlan Wang, Amalia Rapakousiou, Jaime Ruiz, and Didier Astruc

Chem. Eur. J . 2014, 20, 11176 – 11186

Fast-Growing Field of Magnetically Recyclable Nanocatalysts

Dong Wang and Didier Astruc

Chem. Rev .2014, 114, 6949−6985

Mixed-valent metallodendrimers: design and functions

Didier Astruc, Amalia Rapakousiou, Yanlan Wang, Rodrigue Djeda, Abdou Diallo, Jaime Ruiz, Catia Ornelas.

Journal of Coordination Chemistry/ DOI: 10.1080/00958972.2014.939648


“ Click” Synthesis of Nona-PEG-branched Triazole Dendrimers and Stabilization of Gold Nanoparticles That Efficiently Catalyze p-Nitrophenol Reduction

Na Li, María Echeverría, Sergio Moya, Jaime Ruiz, and Didier Astruc.

Inorg. Chem . 2014, 53, 6954−6961

ROMP Synthesis of Cobalticenium−Enamine Polyelectrolytes

Yanlan Wang, Amalia Rapakousiou, and Didier Astruc

Macromolecules 2014, 47, 3767−3774.

Click Chemistry of an Ethynylarene Iron Complex: Syntheses, Properties, and Redox Chemistry of Cationic Bimetallic and Dendritic Iron-Sandwich Complexes

Amalia Rapakousiou, Yanlan Wang, Roberto Ciganda, Jean-Michel Lasnier, and Didier Astruc.

Organometallics 2014, 33, 3583−3590